Trichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)(dimethylformamide-κO)indium(III) hemihydrate
نویسندگان
چکیده
The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent In(III) complex mol-ecules with similar structures and one lattice water mol-ecule. In each complex mol-ecule, the In(III) atom is six-coordinated in a distorted octa-hedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-formamide and three facial Cl atoms. In the crystal, the lattice water mol-ecule is linked to the complex mol-ecules via O-H⋯Cl hydrogen bonds. Further weak C-H⋯Cl and C-H⋯O hydrogen bonds result in the formation of a three-dimensional structure.
منابع مشابه
Trichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)(methanol-κO)indium(III)
In the mol-ecule of the title compound, [InCl(3)(C(12)H(12)N(2))(CH(4)O)], the In(III) atom is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol molecule and three Cl atoms. In the crystal structure, inter-molecular O-H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to [001].
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In the title compound, [In(C(11)H(10)N(2))Cl(3)(C(2)H(6)OS)], the In(III) cation is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethyl-sulfoxide group and three Cl(-) anions. Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds and intra-molecular C-H⋯Cl hydrogen bonds are present in the structure.
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In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol mol-ecule and three Cl atoms. In the crystal, inter-molecular O-H⋯O and O-H⋯Cl hydrogen bonds link the complex and solvent methanol mol-ecules. Intra-molecular C...
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